Stanene possesses excellent properties, including an extremely high charge carrier density, massless Dirac fermions, and high thermal conductivity. Moreover, it exhibits band inversion phenomena, being made a candidate for a topological insulator. Topological insulators can generate dissipationless electric currents under certain conditions, showing great application potentials. However, the presence of a Dirac cone in the band structure of stanene at the high-symmetry point Kin the Brillouin zone, resulting in a zero band gap, significantly limits its applications in the semiconductor field. This study adopts the method of doping B/N elements in stanene and applying an electric field perpendicular to the stanene to open the band gap at the Kpoint. The effects of doping and the intensity of the applied electric field on the structural and electronic properties of stanene are investigated. The results reveal that both doping B elements and applying a vertical electric field can open the band gap at the Kpoint while preserving the topological properties of stanene. Additionally, there is a positive correlation between the applied vertical electric field intensity and the band gap at the Kpoint. Simultaneously doping B elements and applying a vertical electric field can increase the band gap at the Kpoint, reaching 0.092 eV when the electric field intensity is 0.5 V/Å. After doping N elements, stanene is transformed into an indirect band gap semiconductor with a band gap of 0.183 eV. Applying a vertical electric field cannot change the structure of N-doped stanene, and the intensity of the applied vertical electric field is negatively correlated with the band gap at the Kpoint. When the electric field intensity is 0.5 V/Å, the band gap at the Kpoint decreases to 0.153 eV.