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Electron transfer in heavy particle collisions, involving complicated electron correlation mechanisms, greatly affects the charge state balance in plasma, and is also one of important sources for X-ray radiation. Electron transfer cross section and rate coefficient are important atomic parameters required for the development of nuclear fusion plasma in the national defense industry. We systematically investigate the electron transfer process of proton impacting boron atom in an energy range of
${10}^{-3}-{10}^{3}\;{\rm{e}}{\rm{V}}/{\rm{u}}$ based on a fully quantum non-radiative molecular orbital close-coupling method. A total of 15 channels of electron transfer, excitation, and elastic scattering are obtained by using the multi-reference configuration interaction method, and the corresponding molecular energy of each channel is in good agreement with the experimental results. The phenomenon of avoiding crossing between the adiabatic potential energy curves of molecular states is obvious, which constituents the main pathway of electron transfer. The calculation shows that the electron transfer of the 2s orbital is dominated in the process of proton impacting boron atom, while the electron transfer of the 2p orbital contributes a little. In the low energy region, there are obvious quantum resonances in the electron transfer cross section, which originate from the coupling between high energy channel and low energy channel. In addition, we calculate the electron transfer rates of proton-impact boron atom at different temperatures, which can provide important atomic parameter which support for simulating and diagnosing complex plasma environments.-
Keywords:
- electron transfer/
- heavy ion collision/
- potential curve
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原子态 分子态 能量/eV 理论 实验 误差 $ {{\rm{B}}}^{+}\left(1{{\rm{s}}}^{2}2{{\rm{s}}}^{2}\right)+{\rm{H}}\left(1{\rm{s}}\right) $ $ 1{}_{}{}^{2}{{{\Sigma }}}^{+} $ 0 0 0 $ {{\rm{B}}}^{+}\left(1{{\rm{s}}}^{2}2{{\rm{s}}}^{}2{\rm{p}}\right)+{\rm{H}}\left(1{\rm{s}}\right) $ $ 2{}_{}{}^{2}{{{\Sigma }}}^{+}1{}_{}{}^{2}{{\Pi }} $ 4.6226 4.6230 0.0004 $ {{\rm{B}}}^{}\left(1{{\rm{s}}}^{2}2{{\rm{s}}}^{2}2{\rm{p}}\right)+{{\rm{H}}}^{+} $ $ 3{}_{}{}^{2}{{{\Sigma }}}^{+}2{}_{}{}^{2}{{\Pi }} $ 5.3042 5.3003 0.0039 $ {{\rm{B}}}^{+}\left(1{{\rm{s}}}^{2}2{{\rm{s}}}^{}2{\rm{p}}\right)+{\rm{H}}\left(1{\rm{s}}\right) $ $ 4{}_{}{}^{2}{{{\Sigma }}}^{+}3{}_{}{}^{2}{{\Pi }} $ 9.0663 9.1001 0.0338 $ {{\rm{B}}}^{+}\left(1{{\rm{s}}}^{2}2{{\rm{s}}}^{2}\right)+{\rm{H}}\left(2{\rm{p}}\right) $ $ 5{}_{}{}^{2}{{{\Sigma }}}^{+}4{}_{}{}^{2}{{\Pi }} $ 10.1769 10.1987 0.0218 $ {{\rm{B}}}^{+}\left(1{{\rm{s}}}^{2}2{{\rm{s}}}^{2}\right)+{\rm{H}}\left(2{\rm{s}}\right) $ $ 6{}_{}{}^{2}{{{\Sigma }}}^{+} $ 10.1929 10.1987 0.0058 $ {{\rm{B}}}^{}\left(1{{\rm{s}}}^{2}2{{\rm{s}}}^{2}3{\rm{s}}\right)+{{\rm{H}}}^{+} $ $ 7{}_{}{}^{2}{{{\Sigma }}}^{+} $ 10.2615 10.2597 0.0018 $ {{\rm{B}}}^{}\left(1{{\rm{s}}}^{2}2{\rm{s}}2{{\rm{p}}}^{2}\right)+{{\rm{H}}}^{+} $ $ 8{}_{}{}^{2}{{{\Sigma }}}^{+}5{}_{}{}^{2}{{\Pi }} $ 11.2491 11.2337 0.0154 $ {{\rm{B}}}^{}\left(1{{\rm{s}}}^{2}2{{\rm{s}}}^{2}3{\rm{s}}\right)+{{\rm{H}}}^{+} $ $ 9{}_{}{}^{2}{{{\Sigma }}}^{+}6{}_{}{}^{2}{{\Pi }} $ 11.3623 11.3273 0.0350 
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$ T/{\rm{K}} $ $ 2 $ $ 5 $ $ 10 $ $ 40 $ $\alpha /\left({10}^{-12}~{ {\rm{c} }{\rm{m} } }^{3}{\cdot{\rm{s} } }^{-1}\right)$ $ 1.72\times {10}^{-8} $ $ 5.09\times {10}^{-4} $ $ 1.40\times {10}^{-2} $ $ 1.24\times {10}^{-1} $ $ T/{\rm{K}} $ $ 100 $ $ 500 $ $ 1000 $ $ 6000 $ $\alpha /\left({10}^{-14}~{ {\rm{c} }{\rm{m} } }^{3}{\cdot{\rm{s} } }^{-1}\right)$ $ 14.7 $ $ 10.3 $ $ 8.62 $ $ 46.9 $ $T/{(10}^{5}~{\rm{K} })$ $ 0.1 $ $ 0.5 $ $ 1.0 $ $ 5.0 $ $\alpha /\left({10}^{-12}~{ {\rm{c} }{\rm{m} } }^{3}{\cdot{\rm{s} } }^{-1}\right)$ $ 1.72 $ $ 8.91\times {10}^{1} $ $ 3.86\times {10}^{2} $ $ 4.74\times {10}^{3} $ $T/{(10}^{6}~{\rm{K} })$ $ 1.0 $ $ 5.0 $ $ 10 $ $ 50 $ $\alpha /\left({10}^{-9}~{ {\rm{c} }{\rm{m} } }^{3}{\cdot{\rm{s} } }^{-1}\right)$ $ 9.38 $ $ 25.8 $ $ 26.8 $ $ 7.19 $ DownLoad:
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[1] [2] [3] [4] [5] [6] [7] [8] [9] [10] [11] [12] [13] [14] [15] [16] [17] [18] [19] [20] [21] [22] [23] [24] [25]
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