\begin{document}$ \propto \eta\cdot I $\end{document} within general current (I) range. Surprisingly, although the MEL value of the device coexisting with exciplex and electroplex is also greater than the MC value at low current, MEL value is less than MC value at high current. In other words, Mη value of this device undergoes a conversion from positive to negative with current increasing. In this work, to find out the reason why Mη value of exciplex-type OLED formed by TAPC and TPBi shows a negative value under high current and also to study the micro-dynamic evolution mechanism of spin-pair states in this device, three OLEDs are fabricated and their luminescence spectra and organic magnetic field effect curves are measured. The results indicate that the electroplex is produced in the exciplex-type OLED formed by TAPC and TPBi. Since the triplet exciton energy of monomers TAPC and TPBi is higher than those of triplet charge-transfer states of exciplex (CT\begin{document}${}_3^{\rm{ex}} $\end{document}), and the CT\begin{document}${}_3^{\rm{ex}} $\end{document} energy is greater than the energy of triplet charge-transfer states of electroplex (CT\begin{document}${}_3^{\rm{el}} $\end{document}), the CT\begin{document}${}_3^{\rm{ex}} $\end{document} energy can only be transferred to CT\begin{document}${}_3^{\rm{el}} $\end{document} through Dexter energy transfer (DET) process without other loss channels. The electroluminescence (EL) spectrum of this device shows that the luminescence intensity of exciplex is greater than that of electroplex, which indicates that the quantity of exciplex is more than that of electroplex. Besides, EL spectra at different currents prove that the formation rate of exciplex is faster than that of electroplex with current increasing. Owing to less quantity of exciplex at low current, the DET process from CT\begin{document}${}_3^{\rm{ex}} $\end{document} to CT\begin{document}${}_3^{\rm{el}} $\end{document} is too weak to facilitate the RISC process of charge-transfer states of electroplex (CTel). Therefore, the low field amplitude of Mη curve is positive at low current. The number of spin-pair states of exciplex increases with current increasing, which enhances the DET process. These processes of direct charge carriers trapped and energy transferred critically increase the number of CT\begin{document}${}_3^{\rm{el}} $\end{document} at high current, which greatly strengthens the RISC process of CTel. Therefore, the low field amplitude of Mη curve changes from positive to negative with current increasing. Furthermore, the Mη curves of this device are measured when only exciplex exists and only electroplex exists in the employing filter, respectively. As expected, the results confirm the accuracy of the mechanism of the negative value of the total Mη for this device. Obviously, this work contributes to the comprehension of the internal micro-physical mechanism in OLEDs and the law of interactions between excited states."> - 必威体育下载

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Wu Yu-Ting, Zhu Hong-Qiang, Wei Fu-Xian, Wang Hui-Yao, Chen Jing, Ning Ya-Ru, Wu Feng-Jiao, Chen Xiao-Li, Xiong Zu-Hong
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  • Abstract views:4191
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  • Received Date:30 June 2022
  • Accepted Date:02 August 2022
  • Available Online:07 November 2022
  • Published Online:20 November 2022

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