- 必威体育下载

姓名
邮箱
手机号码
标题
留言内容
验证码

Abstract

Na-ion batteries possess great potential applications in the large-scale energy storage. The Na-ion layered oxide cathode (Na _xTMO ₂) has received increasing attention in scientific and industrial research due to its high capacity, easy manufacture, adjustable voltage, and low cost. However, the larger the Na ⁺radius and the stronger the Na ⁺-Na ⁺electrostatic repulsion is, which will lead to various structural configurations and complex structural transitions, resulting in multiple structure-property connections. In this paper, the structural types of Na-ion layered transition metal oxide cathode materials are introduced, and their structural evolutions during Na ⁺de/intercalation are summarized for revealing the mechanism for structural transformation of Na-ion layered transition-metal oxide cathode material and its effect on electrochemical performance; the existing challenges are discussed; the improvement strategies are proposed finally.

Keywords:

Authors and contacts

Corresponding author:Rong Xiao-Hui,rong@iphy.ac.cn; Hu Yong-Sheng,yshu@iphy.ac.cn

Funds:Project supported by the National Natural Science Foundation of China (Grant Nos. 51725206, 52122214, 52072403), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA21070500), Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. 2020006), the China Postdoctoral Science Foundation (Grant No. 2021M703460), and the Natural Science Foundation of Beijing, China (Grant No. 2212022).

FullText HTML: translate this paragraph

References

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]
[28]
[29]
[30]
[31]
[32]
[33]
[34]
[35]
[36]
[37]
[38]
[39]
[40]
[41]
[42]
[43]
[44]
[45]
[46]
[47]
[48]
[49]
[50]
[51]
[52]
[53]
[54]
[55]
[56]
[57]
[58]
[59]
[60]
[61]
[62]
[63]
[64]
[65]
[66]
[67]
[68]
[69]
[70]
[71]
[72]
[73]
[74]
[75]
[76]
[77]
[78]
[79]

Cited By

DownLoad: Full-Size Img PowerPoint

结构	空间群 (代号)	原子占位
结构		Na_e	Na_f	Na	M	O
O3	${R}\bar{3}{m}$ (167)	—	—	3b (0, 0, 1/2)	3a (0, 0, 0)	6c (0, 0, ~0.27)
O'3	C2/m (12)	—	—	2d (0, 1/2, 1/2)	2a (0, 0, 0)	4i (~0.28, 0, ~0.8)
P3	R3m (160)	—	—	3a (0, 0, ~0.17)	3a (0, 0, 0)	3a (0, 0, ~0.4)
P2	P6₃/mmc (194)	2d (2/3, 1/3, 1/4)	2b (0, 0, 1/4)	—	2a (0, 0, 0)	4f (1/3, 2/3, ~0.09)
O2	P6₃mc (186)	—	—	2b (1/3, 2/3, ~0.24)	2b (2/3, 1/3, 0)	2b (2/3, 1/3, ~0.39)

DownLoad: CSV

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]
[28]
[29]
[30]
[31]
[32]
[33]
[34]
[35]
[36]
[37]
[38]
[39]
[40]
[41]
[42]
[43]
[44]
[45]
[46]
[47]
[48]
[49]
[50]
[51]
[52]
[53]
[54]
[55]
[56]
[57]
[58]
[59]
[60]
[61]
[62]
[63]
[64]
[65]
[66]
[67]
[68]
[69]
[70]
[71]
[72]
[73]
[74]
[75]
[76]
[77]
[78]
[79]

[1]	Zhou Xuan-Chi, Li Hai-Fan.Research on the electronic phase transitions in strongly correlated oxides and multi-field regulation. Acta Physica Sinica, 2024, 73(11): 117102.doi:10.7498/aps.73.20240289
[2]	Ran Pei-Lin, Wu Kang, Zhao En-Yue, Wang Fang-Wei, Wu Zhi-Min.Enhancing reversible capacity and cycling stability of Li_1.2Ni_0.13Fe_0.13Mn_0.54O₂by inducing low Li/Ni misalignment through Mo doping. Acta Physica Sinica, 2024, 73(2): 028201.doi:10.7498/aps.73.20231361
[3]	Yang Yuan, Hu Nai-Fang, Jin Yong-Cheng, Ma Jun, Cui Guang-Lei.Research advance of lithium-rich cathode materials in all-solid-state lithium batteries. Acta Physica Sinica, 2023, 72(11): 118801.doi:10.7498/aps.72.20230258
[4]	Xu Wei-Liang, Dang Rong-Bin, Yang Yang, Guo Qiu-Bo, Ding Fei-Xiang, Han Shuai, Tang Xiao-Han, Liu Yuan, Zuo Zhan-Chun, Wang Xiao-Qi, Yang Rui, Jin Xu, Rong Xiao-Hui, Hong Juan, Xu Ning, Hu Yong-Sheng.Magnesium doping improved characteristics of high voltage cycle of layered cathode of sodium ion battery. Acta Physica Sinica, 2023, 72(5): 058802.doi:10.7498/aps.72.20222098
[5]	Liu Qiang, Ni Yao, Liu Lu, Sun Lin, Liu Jia-Qi, Xu Wen-Tao.Artificial synapses based on layered multi-component metal oxides. Acta Physica Sinica, 2022, 71(14): 148501.doi:10.7498/aps.71.20220303
[6]	Chen Si-Yu, Ye Xiao-Juan, Liu Chun-Sheng.Theoretical research of two-dimensional germanether in sodium-ion battery. Acta Physica Sinica, 2022, 71(22): 228202.doi:10.7498/aps.71.20220572
[7]	Zhang Yong-Quan, Yao An-Quan, Yang Liu, Zhu Kai, Cao Dian-Xue.Preparation and electrochemical performance of sodium manganese oxides as cathode materials for aqueous Mg-ion batteries. Acta Physica Sinica, 2021, 70(16): 168201.doi:10.7498/aps.70.20202130
[8]	Xu Han, Zhang Lu, Dang Zheng.Coupling mechanism of mass transport and electrochemical reaction within patterned anode of solid oxide fuel cell. Acta Physica Sinica, 2020, 69(9): 098801.doi:10.7498/aps.69.20191697
[9]	Lin Chuan-Jin, Zheng Feng, Zhu Zi-Zhong.Electronic structures and Li diffusion in cathode material Li₂FeO₂of Li-ion batteries. Acta Physica Sinica, 2019, 68(15): 157201.doi:10.7498/aps.68.20190213
[10]	Sun Xiao-Ning, Qu Zhao-Ming, Wang Qing-Guo, Yuan Yang, Liu Shang-He.Research progress of metal-insulator phase transition in VO₂induced by electric field. Acta Physica Sinica, 2019, 68(10): 107201.doi:10.7498/aps.68.20190136
[11]	Zheng Lu-Min, Zhong Shu-Ying, Xu Bo, Ouyang Chu-Ying.First-principles study of rare-earth-doped cathode materials Li₂MnO₃in Li-ion batteries. Acta Physica Sinica, 2019, 68(13): 138201.doi:10.7498/aps.68.20190509
[12]	Lu Ya-Xiang, Zhao Cheng-Long, Rong Xiao-Hui, Chen Li-Quan, Hu Yong-Sheng.Research progress of materials and devices for room-temperature Na-ion batteries. Acta Physica Sinica, 2018, 67(12): 120601.doi:10.7498/aps.67.20180847
[13]	Liu Chang-Wen, Zhou Xun, Yue Wen-Jin, Wang Ming-Tai, Qiu Ze-Liang, Meng Wei-Li, Chen Jun-Wei, Qi Juan-Juan, Dong Chao.Hybrid polymer-based solar cells with metal oxides as the main electron acceptor and transporter. Acta Physica Sinica, 2015, 64(3): 038804.doi:10.7498/aps.64.038804
[14]	Ma Hao, Liu Lei, Lu Xue-Sen, Liu Su-Ping, Shi Jian-Ying.Electronic structure and transport properties of cathode material Li2FeSiO4 for lithium-ion battery. Acta Physica Sinica, 2015, 64(24): 248201.doi:10.7498/aps.64.248201
[15]	Yu Hai-Ling, Zhu Jia-Qi, Cao Wen-Xin, Han Jie-Cai.Process in preparation of metal-catalyzed graphene. Acta Physica Sinica, 2013, 62(2): 028201.doi:10.7498/aps.62.028201
[16]	Lu Zhi-Peng, Zhu Wen-Jun, Lu Tie-Cheng.Ab initio study of the bcc-to-hcp transition mechanism in Fe under pressure. Acta Physica Sinica, 2013, 62(5): 056401.doi:10.7498/aps.62.056401
[17]	Ren Xiao-Dong, Liu Jian-Jun, Zhang Wen-Qing.Strain effect on the intercalation potential of the layered Mn-contained lithium ion batteries cathode materials: a first principles method. Acta Physica Sinica, 2012, 61(18): 183101.doi:10.7498/aps.61.183101
[18]	Bai Ying, Wang Bei, Zhang Wei-Feng.Nano-LiNiO2 as cathode material for lithium ion battery synthesized by molten salt method. Acta Physica Sinica, 2011, 60(6): 068202.doi:10.7498/aps.60.068202
[19]	Yue Min, Hu She-Jun, Hou Xian-Hua, Liang Qi, Peng Wei.Preparation and characterization of positive materials LiMn1-xFexPO4(0x<1) for lithium ion batteries. Acta Physica Sinica, 2011, 60(3): 038202.doi:10.7498/aps.60.038202
[20]	Ouyang Chu-Ying, Hu Guo-Jin.Influence of surface effect to the performance of LiMn2O4 cathode material for lithium ion batteries. Acta Physica Sinica, 2010, 59(8): 5863-5869.doi:10.7498/aps.59.5863

Catalog

Vol. 71, Issue 10 - 2022-05-20

Metrics

Abstract views:19766
PDF Downloads:1008
Cited By:0

Search

Article