- 必威体育下载

姓名
邮箱
手机号码
标题
留言内容
验证码

Abstract

In order to break through the limit of Shockley-Queisser (SQ) radiation and further improve the efficiency of perovskite solar cells, tin-lead perovskite solar cells have widely and successfully been used as narrow-bandgap bottom cells in all-perovskite tandem solar cells. The highest efficiency of tin-lead perovskite solar cells has recently reached 21.7%, which, however, is still lower than that of lead-based perovskite solar cells. This article analyzes the main factors that limit the further improving of their performances, and summarizes the effective solutions proposed by researchers in recent years. The main points are as follows: 1) by adding tin-rich additives, strong reducing agents or compounds containing large organic cations, Sn ²⁺oxidation is inhibited and the p-doped degree of tin-lead perovskite and the open-circuit voltage loss are reduced; 2) through regulating the composition, changing the method of preparing the perovskite film, adding functional groups or solvent engineering, the crystallization rate of tin-lead perovskite film is delayed and the crystallization quality of the film is improved; 3) by selecting an appropriate electron transport layer or hole transport layer the influence of energy level mismatch on carrier transport or the instability of carrier transport layer on devices can be avoided. Finally, the future development of Sn-Pb perovskite solar cells is prospected. It is believed that the tin-lead perovskite solar cells can realize not only the high efficiency and stable single-junction solar cells, but also high efficiency perovskite-perovskite tandem solar cells.

Keywords:

Authors and contacts

Corresponding author:Zhang Xiao-Dan,xdzhang@nankai.edu.cn

Funds:Project supported by the National Research Program of China (Grant No. 2018YFB1500103), the National Natural Science Foundation of China (Grant No. 61674084), the 111 Project, China (Grant No. B16027), the Tianjin Civil Military Integration Project, China (Grant No. 18ZXJMTG00220), and the Fundamental Research Funds for the Central Universities, China (Grant Nos. 63201171, 63201173)

FullText HTML: translate this paragraph

References

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]
[28]
[29]
[30]
[31]
[32]
[33]
[34]
[35]
[36]
[37]
[38]
[39]
[40]
[41]
[42]
[43]
[44]
[45]
[46]
[47]
[48]
[49]
[50]
[51]
[52]
[53]
[54]
[55]
[56]
[57]
[58]
[59]
[60]
[61]
[62]
[63]
[64]
[65]
[66]
[67]
[68]
[69]
[70]
[71]
[72]
[73]
[74]
[75]
[76]
[77]
[78]
[79]
[80]
[81]
[82]
[83]
[84]

Cited By

DownLoad: Full-Size Img PowerPoint

Year	Perovskite	Device structure	Eg/eV	V_OC/V	J_SC/(mA·cm^–2)	FF/%	PCE/(%)	Ref.
2016	MA_0.5FA_0.5Pb_0.75Sn_0.25I₃	ITO/PEDOT:PSS/PVK/PCBM/Bis-C₆₀/Ag	1.33	0.78	23.03	79	14.19	[49]
2016	(FASnI₃)_0.6(MAPbI₃)_0.4	ITO/PEDOT:PSS/PVK/C₆₀/BCP/Ag	1.25	0.795	26.86	70.6	15.08	[26]
2017	MA_0.5FA_0.5Pb_0.5Sn_0.5I₃	ITO/PEDOT:PSS/PVK/PCBM/Bis-C₆₀/Ag	1.2	0.78	25.69	70	14.01	[38]
2017	MAPb_0.5Sn_0.5I₃	ITO/PEDOT:PSS/PVK-DF-C₆₀/ICBA/Bis-C₆₀/Ag	1.22	0.87	26.1	69	15.61	[72]
2018	(t-BUA)₂(FA_0.85Cs_0.15)_n–1Pb_0.6Sn_0.4)_nI_3n+1	ITO/PEDOT:PSS/2 D-PVK/PCBM/BCP/Ag	1.24	0.70	24.2	63	10.6	[43]
2018	FA_0.6MA_0.4Sn_0.6Pb_0.4I₃	ITO/PFI-(PEDOT:PSS)/PVK/PCBM/BCP/Ag	1.22	0.784	27.22	74.36	15.85	[81]
2018	(FAPbI₃)_0.7(CsSnI₃)_0.3	ITO/PEDOT:PSS/PVK/C₆₀/BCP/Al	1.3	0.74	25.89	81.4	15.6	[36]
2018	(FASnI₃)_0.6(MAPbI₃)_0.34(MAPbBr₃)_0.06	ITO/PEDOT:PSS/PVK/C₆₀/BCP/Ag	1.272	0.888	28.72	74.6	19.03	[53]
2018	(FASnI₃)_0.6(MAPbI₃)_0.4	ITO/PEDOT:PSS/PVK/C₆₀/BCP/Ag	1.25	0.841	29.0	74.4	18.1	[30]
2018	FAPb_0.7Sn_0.3I₃	ITO/PEDOT:PSS/PVK/PEAI/PC₆₁BM/BCP/Ag	1.34	0.78	26.46	79	16.26	[54]
2018	FAPb_0.75Sn_0.25I₃	ITO/NiO_X/PVK/PC₆₀BM/BCP/Ag	1.36	0.81	28.23	75.4	17.25	[27]
2018	(FASnI₃)_0.6(MAPbI₃)_0.4	ITO/PEDOT:PSS/PBDBT:ITIC/PVK/C₆₀/BCP/Ag	1.25	0.86	27.92	75.1	18.03	[82]
2019	FA_0.8MA_0.2Sn_0.5Pb_0.5I₃	ITO/PEDOT:PSS/PVK/PCBM/BCP/Ag	1.27	0.81	30	75	18.2	[61]
2019	(FAPb_0.6Sn_0.4I₃)_0.85(MAPb_0.6Sn_0.4Br₃)_0.15	ITO/PEDOT:PSS/PVK/PCBM/BisC₆₀/Ag	1.28	0.87	26.45	79.1	18.21	[39]
2019	FA_0.7MA_0.3Pb_0.5Sn_0.5I₃	ITO/PEDOT:PSS/PVK/PC₆₀BM/BCP/Cu	1.22	0.831	31.4	80.8	21.1	[18]
2019	Cs_0.1MA_0.2FA_0.7Pb_0.5Sn_0.5I₃	ITO/NiO_X/PVK/C₆₀/BCP/Cu	1.2	0.771	31.1	73.3	17.6	[52]
2019	FA_0.75Cs_0.25Sn_0.4Pb_0.6I₃	ITO/PVK/C₆₀/BCP/Ag	1.25	0.72	32.59	69.8	16.4	[51]
2019	(FASnI₃)_0.6(MAPbI₃)_0.4	ITO/PEDOT:PSS/PVK/C₆₀/BCP/Ag	1.25	0.834	30.4	80.8	20.5	[55]
2019	Cs_0.1MA_0.2FA_0.7Sn_0.5Pb_0.5I₃	ITO/NiO_X/PVK/C₆₀/BCP/Cu	1.2	0.771	31.1	73.3	17.6	[52]
2020	(MAPbI₃)_0.75(FASnI₃)_0.25	ITO/PEDOT:PSS/PVK/BCP/Ag	1.33	0.79	28.42	78	17.51	[44]
2020	Cs_0.1MA_0.2FA_0.7Pb_0.5Sn_0.5I₃	ITO/PEDOT:PSS/PVK/PCBM/PEIE/Ag	1.25	0.81	30.3	78.9	19.4	[42]
2020	FA_0.83Cs_0.17Pb_0.7Sn_0.3I₃	ITO/PEDOT:PSS/PVK/PCBM/BCP/Ag	1.3	0.82	30.3	78.4	18.1	[9]
2020	FA_0.7MA_0.3Pb_0.7Sn_0.3I₃	ITO/PEDOT:PSS(EMIC)/PVK/S-acetylthiocholine chlorde/C₆₀/BCP/Ag	1.35	1.02	26.61	76	20.63	[66]
2020	FA_0.66MA_0.34Pb_0.5Sn_0.5I₃	ITO/PEDOT:PSS/PVK/C₆₀/BCP/Ag	1.23	0.78	27.8	73	15.8	[54]
2020	FA_0.5MA_0.45Cs_0.05Pb_0.5Sn_0.5I₃	ITO/PEDOT:PSS/PTAA/Cd-PVK/C₆₀/BCP/Cu	1.22	0.85	30.2	79	20.3	[68]
2020	FA_0.7MA_0.3Pb_0.5Sn_0.5I₃	ITO/PEDOT:PSS/PVK/C₆₀/BCP/Cu	1.24	0.85	31.6	80.8	21.7	[4]

DownLoad: CSV

[1]
[2]
[3]
[4]
[5]
[6]
[7]
[8]
[9]
[10]
[11]
[12]
[13]
[14]
[15]
[16]
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]
[28]
[29]
[30]
[31]
[32]
[33]
[34]
[35]
[36]
[37]
[38]
[39]
[40]
[41]
[42]
[43]
[44]
[45]
[46]
[47]
[48]
[49]
[50]
[51]
[52]
[53]
[54]
[55]
[56]
[57]
[58]
[59]
[60]
[61]
[62]
[63]
[64]
[65]
[66]
[67]
[68]
[69]
[70]
[71]
[72]
[73]
[74]
[75]
[76]
[77]
[78]
[79]
[80]
[81]
[82]
[83]
[84]

[1]	Wang Gui-Qiang, Wang Dong-Sheng, Bi Jia-Yu, Chang Jia-Run, Meng Fan-Ning.Tailoring of CsPbIBr₂perovskite crystallization via phenylthiourea for stable and efficiency perovskite solar cells. Acta Physica Sinica, 2023, 72(15): 158801.doi:10.7498/aps.72.20230593
[2]	Han Xiao-Jing, Yang Jing, Zhang Jia-Li, Liu Dong-Xue, Shi Biao, Wang Peng-Yang, Zhao Ying, Zhang Xiao-Dan.Electron transport layer of tin dioxide deposited by reactive plasma and its application in perovskite solar cells. Acta Physica Sinica, 2023, 72(17): 178401.doi:10.7498/aps.72.20230693
[3]	Sun Xue, Huang Feng, Liu Gui-Xiong, Su Zi-Sheng.Effect of nano-nucleation sites assisted crystallization on performance of perovskite photodetector. Acta Physica Sinica, 2022, 71(17): 178102.doi:10.7498/aps.71.20220189
[4]	Liang Qi, Yang Meng-Qi, Zhang Jing-Yang, Wang Ru-Zhi.PECVD-prepared high-quality GaN films and their photoresponse properties. Acta Physica Sinica, 2022, 71(9): 097302.doi:10.7498/aps.71.20211922
[5]	Wang Pei-Pei, Zhang Chen-Xi, Hu Li-Na, Li Shi-Qi, Ren Wei-Hua, Hao Yu-Ying.Research progress of inverted planar perovskite solar cells based on nickel oxide as hole transport layer. Acta Physica Sinica, 2021, 70(11): 118801.doi:10.7498/aps.70.20201896
[6]	Xu Qing-Lin, Xiang Ting, Xu Wei, Li Ting, Wu Xiao-Yan, Li Wei, Qiu Xue-Jun, Chen Ping.Gold nanoparticals modified indium tin oxide anode for high performance red perovskite light emitting diodes. Acta Physica Sinica, 2021, 70(20): 207803.doi:10.7498/aps.70.20210500
[7]	Chen Long, Chen Cheng-Ke, Li Xiao, Hu Xiao-Jun.Effects of oxidation on silicon vacancy photoluminescence and microstructure of separated domain formed nanodiamond films. Acta Physica Sinica, 2019, 68(16): 168101.doi:10.7498/aps.68.20190422
[8]	Li Ming-Yang, Zhang Lei-Min, Lv Shasha, Li Zheng-Cao.Effects of ion irradiation and oxidation on point defects in IG-110 nuclear grade graphite. Acta Physica Sinica, 2019, 68(12): 128102.doi:10.7498/aps.68.20190371
[9]	Zhao Guo-Dong, Yang Ya-Li, Ren Wei.Recent progress of improper ferroelectricity in perovskite oxides. Acta Physica Sinica, 2018, 67(15): 157504.doi:10.7498/aps.67.20180936
[10]	Yang Meng-Sheng, Yi Tai-Min, Zheng Feng-Cheng, Tang Yong-Jian, Zhang Lin, Du Kai, Li Ning, Zhao Li-Ping, Ke Bo, Xing Pi-Feng.Surface oxidation of as-deposit uranium film characterized by X-ray photoelectron spectroscopy. Acta Physica Sinica, 2018, 67(2): 027301.doi:10.7498/aps.67.20172055
[11]	Wang Dong, Zhu Hui-Min, Zhou Zhong-Min, WangZai-Wei, Lü Si-Liu, Pang Shu-Ping, CuiGuang-Lei.Effect of solvent on the perovskite thin film morphology and crystallinity. Acta Physica Sinica, 2015, 64(3): 038403.doi:10.7498/aps.64.038403
[12]	Li Xiao-Na, Zheng Yue-Hong, Li Zhen, Wang Miao, Zhang Kun, Dong Chuang.High temperature oxidation resistance of cluster model designed alloys Cu-Cu12-[Mx/(12+x)Ni12/(12+x)]5 (M=Si, Cr, Cr+Fe). Acta Physica Sinica, 2014, 63(2): 028102.doi:10.7498/aps.63.028102
[13]	Yi Ding, Qin Wei, Xie Shi-Jie.Investigation of polarons in perovskite manganites. Acta Physica Sinica, 2012, 61(20): 207101.doi:10.7498/aps.61.207101
[14]	Hu Mei-Jiao, Li Cheng, Xu Jian-Fang, Lai Hong-Kai, Chen Song-Yan.Formation and properties of GeOI prepared by cyclic thermal oxidation and annealing processes. Acta Physica Sinica, 2011, 60(7): 078102.doi:10.7498/aps.60.078102
[15]	Xiang Jun, Wang Xiao-Hui.Solid-state reaction synthesis and electrical properties of Sm0.9Sr0.1AlO3-δ perovskite oxide. Acta Physica Sinica, 2008, 57(7): 4417-4423.doi:10.7498/aps.57.4417
[16]	Xie Zi-Li, Zhang Rong, Xiu Xiang-Qian, Liu Bin, Zhu Shun-Ming, Zhao Hong, Pu Lin, Han Ping, Jiang Ruo-Lian, Shi Yi, Zheng You-Dou.The oxidation characteristics of InN films. Acta Physica Sinica, 2007, 56(2): 1032-1035.doi:10.7498/aps.56.1032
[17]	LI Ya, Chen Ling-Yan, Zhang Zhe, Wu Yong-Gang, Qiao Yi, Xu Wei-Xin.. Acta Physica Sinica, 2001, 50(1): 79-82.doi:10.7498/aps.50.79
[18]	JIANG YONG, LI GUANG, ZENG XIANG-YONG, YANG YING-PING, YUAN SONG-LIU, JIN SI-ZHAO.ELECTRONIC SPIN RESONANCE STUDY OF PEROVSKITE-TYPE MANGANITES. Acta Physica Sinica, 2000, 49(9): 1846-1851.doi:10.7498/aps.49.1846
[19]	Yanag Guang-Liang, Xianyu Wen-Xu, Qian Zheng -Nan, Jin Han-Min.. Acta Physica Sinica, 2000, 49(3): 553-556.doi:10.7498/aps.49.553
[20]	LIAN GUI-JUN, LI MEI-YA, KANG JIN-FENG, GUO JIAN-DONG, SUN YUN-FENG, XIONG GUANG-CHENG.EPITAXIAL GROWTH OF PEROVSKITE OXIDE THIN FILMS. Acta Physica Sinica, 1999, 48(10): 1917-1922.doi:10.7498/aps.48.1917

Catalog

Vol. 70, Issue 11 - 2021-06-05

Metrics

Abstract views:10274
PDF Downloads:273
Cited By:0

Search

Article