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Abstract

Piezoelectric ceramics is a versatile functional material that can realize interconversion between electrical energy and mechanical energy. As the electrical properties of piezoelectric ceramics are extremely sensitive to the grain size variation, the investigation of grain size effect has attracted much attention. In this paper, the recent research progress of the grain size effect on perovskite piezoelectric ceramics, including barium titanate (BT), lead zirconate titanate (PZT), potassium sodium niobate (KNN), and sodium bismuth titanate (BNT), is comprehensively reviewed. We especially focus on topics including feasible ways of fabricating piezoelectric ceramics with the desired grain sizes, the influence of the grain size effect on piezoelectric properties, and the corresponding physical mechanisms. This review would be beneficial to understanding the influence of the grain size effect on piezoelectric properties. The review concludes with the prediction of the further investigation on the grain size effect.

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Authors and contacts

Corresponding author:Gong Wen,gongwen@tsinghua-zj.edu.cn; Wang Ke,wang-ke@tsinghua.edu.cn

Funds:Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 51822206), the National Natural Science Foundation of China (Grant No. 51972005), and the Science Challenge Project, China (Grant No. TZ2018003)

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Cited By

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分类	制备方法	最细粉体粒径/nm	文献
气相法	气相合成法	～100	[34]
固相法	固相反应合成法	100	[35]
	研磨-离心法	300	[36]
	高能球磨法	16	[37]
液相法	溶胶-凝胶法	38	[38]
	水热法	< 100	[39,40]
	微波水热法	30	[41]
	溶剂热合成法	20	[42]
	醇盐法	5	[43]
	水解法	100	[44]
	微乳液法	< 10	[45,46]
	低温直接合成法	< 10	[47,48]
其他方法	生物法	4	[49]
其他方法	微模板法	6	[50]

DownLoad: CSV

烧结方法	晶粒尺寸/μm
烧结方法	BT	PZT	KNN
普通烧结	0.5—100^[51,52]	1—10^[25]	0.5—4^[53]
两步法烧结	0.005—8.6^[27,54]	1.6—6.4^[55]	1.6—3.8^[56,57]
热压烧结	0.3—1.2^[23]	2—5^[58]	~0.31^[57]
热等静压烧结	0.32—47.3^[59,60]	2—4^[61]	~0.34^[62]
微波烧结	~3.4^[63]	~2^[64]	< 1^[65]
等离子放电烧结	0.02—1.2^[52,66,67]	0.3—0.5^[68]	0.2—1^[69-71]
闪速烧结	0.3—0.4^[72]	^#0.168—1.4 (AC)^[73] 0.269—4 (DC)^[74]	^*< 0.5&4^[75]
注:^#AC指在交流电场下的闪速烧结, DC指在直流电场下的闪速烧结; ^*晶粒尺寸呈现双峰分布.

DownLoad: CSV

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Vol. 69, Issue 21 - 2020-11-05

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