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Memristor, as a new type of electronic component that can realize high density, multi-function, low power consumption, and multi-level data storage, has brought significant changes to the field of circuit structure design, information storage theory, and artificial synapses simulation. In a wide range of memristors, the protein-based memristors have unparalleled natural advantages in other cutting-edge information technology fields such as implantable computing, human-computer interaction, and human-computer integration due to their controllable degradation, rich and cheap raw materials, and biocompatibility. Therefore, the memristor is considered as the most potential candidate for building the next generation of high-tech information electronic device. In this article, the latest research progress of protein based memristors is comprehensively reviewed. The research progress of other proteins, including the widely studied egg albumen and artificial recombinant protein with excellent performance are first summarized, and then the research process of silk fibroin-based memristors, the performance improvement of silk fibroin-based memristors brought by functional strategies are comprehensively introduced. The Structure-activity relationship between structure and performance of functionalized silk fibroin is analyzed. Finally, the performance of the protein-based memristor is comprehensively analyzed, and the future development opportunities of the green electronic device are also prospected.
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Keywords:
- mesoscopic functionalization/
- protein/
- memristor/
- electronic devices
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器件结构 开关比 开关电压/V 保持时长/s 擦写速度/ns 循环次数 Al/蚕丝蛋白/ITO[61] 10 10.4/–11.5 — — — Ag/蚕丝蛋白/Au[63] 107 1.3—3.4/–1.3 4.5 × 103 — — Ag/蚕丝蛋白/Au[64] 105 0.7—1.7/–1.2 104 — 30 Mg/蚕丝蛋白/Mg[65] 104 0.7—1.7/–1 104 — 50 Au/蚕丝蛋白/Pt[74] 104 3/–1.7 5.7 × 103 — 30 Al/CdSe-蚕丝蛋白/ITO[73] — — 104 — — Ag/Au-蚕丝蛋白/ITO[68] 102 0.4/–0.2 1.4 × 104 — 100 Ag/Ag-蚕丝蛋白/ITO[24] 103 0.3/–0.18 104 10 100 Al/CDs-蚕丝蛋白/ITO[70] — 3/–1 106 — 100 W/鸡蛋白蛋白/ITO[32] 102 2/7 — — 100 Ag/鸡蛋白蛋白/Al[75] 102 0.6/–0.7 104 75 50 Pt/铁蛋白/Pt[34] 105 2.2/–1.1 6 × 103 — 70 Ag/丝胶蛋白/Au[33] 106 2.5/–0.8 103 — 21 Al/S-layer/ITO[35] 6.2 8/–8 4 × 103 — 500 Cu/rDnaj/Pt[41] 106 0.12/–0.08 106 — 100 Ag/角蛋白/FTO[50] 103 1.5/–1.5 104 — 100 Ag/溶菌酶/Pt[47] 106 1/–1.3 104 100 200 -
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