Femtosecond streak camera is currently the only diagnostic device with a femtosecond time resolution. Scanning circuit with bilateral symmetrical output is an important part of femtosecond streak camera. To achieve better performance of the streak camera, high requirements are placed on the output of scanning circuit. Owing to the excellent feature of litter time jitter and fast response speed, a GaAs photoconductive semiconductor switch (PCSS) has become a core device in the scanning circuit. Investigating the positive and negative symmetric pulses with fast rising edgeof GaAs PCSS is of great significance to improving the time resolution of femtosecond streak camera. In this paper, a laser with a pulse width of 60 fs was used to trigger a GaAs PCSS with an electrode gap of 3.5 mm. Under different storage capacitors and bias voltages, the positive and negative symmetric pulses withthe fastest rise time of 149 ps and the highest voltage transmission efficiency of 92.9% were obtained. The test results meet the design requirements of streak camera to realize femtosecond time resolution. Through the comparative analysis of the experimental values, it is concluded that the storage capacitor can affect the efficiency and rise time of the output electrical pulse in the same trigger laser pulse. By calculating the multiplication rate of carriers in combination with the output electrical pulse waveform, it is concluded that the GaAs PCSS operates in linear mode. According to the working characteristics of the linear mode and the energy storage characteristics of the capacitor, the analysis indicates that, when the characteristics of the trigger laser pulse are the same, the transmission efficiency and rise time of the output electric pulse voltage increase with the increase in storage capacitor, which is consistent with the experimental results. This study has a certain guiding significance for the better application of GaAs PCSS in femtosecond streak camera, which also has a certain propelling effect on improving the time resolution of femtosecond streak camera.