The interference characteristics of normal modes in low-frequency broadband sound can be applied to source localization and environmental parameter inversion in shallow water. However, the identification ambiguity of interference normal mode pairs generally occurs in practical applications due to unknown source position, some weakly-excited normal modes, mismatched environmental model, etc. For the applications of a horizontal line array, a model-based processing approach is proposed to determine the orders of the interference normal mode pairs based on the intrinsic dispersion characteristics of interference normal mode pairs in the received signals and the range-independent properties of the array beam output angles. Firstly, the normal mode pair filtering is achieved by using the WARPING transform of the signal autocorrelation function in the element domain of the horizontal line array. Then, the arrival angles of the filtered interference normal mode pairs are estimated by using array beamforming. Finally, the estimated beam output angles are matched with the replica values computed by sound field model. The approach is verified by using the explosive pulse signals received by the seafloor-deployed 32-element horizontal line array at the North Yellow Sea in 2011. Furthermore, some simulations are involved to analyze the effects of environmental parameter mismatches including water sound speed profile, sea bottom parameters and water depth on the identification performance of interference normal mode pairs. The results show that the water depth is a major factor influencing the extracted values of the beam output angles of interference normal mode pairs. The approach might fail when the water depth mismatch exceeds 14% of the practical value. However, the effects of water sound speed profile mismatch and sea bottom parameters mismatch are negligible. The effect of signal-to-noise ratio in the element domain on a horizontal line array is also simulated in order to analyze the limitation of identification performance, which shows that the required signal-to-noise ratio in the element domain should be more than 2 dB.