Sintering plays a decisive role to determine final product quality in the powder metallurgy process. Understanding the law of structure and defects as well as determining the initial sintering temperature and crystallization temperature will prove clear information to determine favorable sintering technology for the powder compacted billet. In this paper, the internal friction characteristics in the sintering process for powder compact billet, pure Al, Mg, Cu, Fe are systematically studied in terms of internal friction technology. Two internal friction peaks, named heating peak and cooling peak are respectively found in the first run. The cooling peak is a stable relaxational internal friction peak. It is concluded that the peak is associated with the viscous sliding of grain boundary based on the activation energy and peak temperature location. The heating peak is an unstable internal friction peak corresponding to the decline of resistance and relative dynamic modulus, the peak temperature being considered as an initial sintering temperature due to the great change of material performance. Furthermore, the heating peak is dependent on powder particle size and compressing pressure, which increases with the decrease of particle size or compressing pressure. The dependence can be understood according to the increase of weak bonding interface and activated slipping distance between powder particles. The internal friction of the powder compacted billet in the heating process gradually increases with the temperature increasing, which is mainly due to the micro sliding of the weak bonding interface, but the enhancing trend stops and internal friction rapidly declines when the temperature approaches to the peak location due to the transition of weak bonding interface to grain boundary, as a result, leading to the formation of the heating peak. The occurrence of therising temperature peak indicates the formation of grain boundary between powder particles in the sintering process of powder compacted billet. Correspondingly, the peak temperature can be used as a crystallization temperature.