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We have developed a method to evaluate the effective vibration rotation parameter using the wavefunction from the local mode model, on the basis of the wavefunction equivalence of the two models describing the stretching overtone——the NMDD normal mode model and HCAO local mode model. By using this approach, an improved “α-relation” is derived, which exists among the effective vibration rotation parameters of local mode vibrational state at the local mode limit.
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