For discrete optical systems integrated into optical fibers, the optical fields of the individual waveguides are coupled and correlated with each other. This paper studies how to adjust the refractive index of discrete waveguides by thermal diffusion, so as to enhance the coupling between discrete waveguides, and also constructs the discrete waveguide thermally diffused model and the thermally diffused coupling model of twin-core and three-core fibers. The multicore fiber is heated different times by a hydrogen-oxygen flame, and the outgoing light field at the end face of the optical fiber is monitored at the same time. Then, the three-dimensional refractive index measurement results of the thermally diffused multicore fiber verify the feasibility of thermal diffusion technology to change the refractive index of discrete waveguides for coupling. Thermal diffusion technology can be used to fabricate multicore fiber couplers. By combining multicore fiber and core-by-core inscribed fiber Bragg grating technology and by using thermal diffusion technology, the single-channel sensing measurement can be realized. The method of changing the refractive index of discrete waveguides through thermal diffusion has the advantages of high integration, high stability, and mass fabrication. The research on the thermal diffusion of discrete waveguides can improve the application potential of multicore fiber sensing systems, and promote the broad application of discrete waveguide structure optical fiber in the fields of optical communication, optical sensing, biomedicine, and artificial intelligence.