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摘要

为了进一步研究Sr ₂CuO _3.4高温超导样品中调制结构与超导电性关系, 本文对其调制结构形成机制提出了一种新的解释. 采用同步辐射共振X射线衍射技术在Cu K边附近探测调制结构随入射光能量的变化, 探测到Cu ²⁺, Cu ³⁺变价有序, 并用于解释Sr ₂CuO _3.4高温超导样品中调制结构的形成机制. 实验结果表明, 氧空位既占据顶角位置又存在于CuO ₂面内, 氧空位的有序排布造成变价铜离子有序, 这种有序结构与其超导电性相关.

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Abstract

Sr ₂CuO _3+δis cuprate, a high temperature superconducting (HTS) material that has a single copper oxide layer and a relatively high critical temperature. Its structure is simple and contains fewer atoms, but there are many modulation structures in it. A lot of studies have pointed out that the modulation structure is related to its superconductivity. In order to further study the relationship between modulated structure and superconductivity in Sr ₂CuO _3.4HTS sample, a new explanation for the formation mechanism of modulation structure is proposed in this paper. The synchrotron radiation resonant X-ray diffraction (RXD) technique is used to detect the variation of modulation structure near the absorption edge of Cu atom. Cu ²⁺, Cu ³⁺valence order is detected and used to explain the formation mechanism of modulation structure in Sr ₂CuO _3.4high temperature superconducting sample. The energy values of incident light are selected to be 8.52, 8.95, 8.98, 9.05, 9.5, and 10.0 keV near the edge of Cu K. The energy resolution is about 1.5 eV. The detector used in the experiment is Mar165 CCD surface detector. The distance from the detector to the sample is about 315 mm. The two-dimensional diffraction pattern recorded by the CCD plane detector is processed by Fit2D software to obtain the diffraction integral intensity. In addition, the energy calibration for each of the copper foil samples is carried out prior to the start of the experiment and in the process of varying energy value. The experimental results show that the Bragg diffraction peaks corresponding to T _c= 48 K and the modulation structures of Fmmmand Pmmmare visible and calibrated. The intensity of the corresponding (2/5, 4/5, 0) diffraction peak of Fmmmis energy-dependent near the Cu Kedge and first increases and then decreases abruptly near the absorption edge. This indicates that a stable ordered arrangement structure of Cu ²⁺and Cu ³⁺is formed at this time. The weak diffraction signal of this ordered arrangement structure confirms the fact that the copper-O bonding is stronger. The experiments indicate that oxygen vacancies occupy both the apical position and the CuO ₂plane. The ordering arrangement of oxygen vacancies results in the ordering of copper ions with variable valence. The Cu ²⁺, Cu ³⁺valence order is related to the superconductivity of Sr ₂CuO _3.4.

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通信作者:张丽,wanghaibo014@126.com

基金项目:国家自然科学基金(批准号: WK2310000043)和吉林省教育厅“十三五”科学技术课题(批准号: JJKH20180860KJ)资助的课题.

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Corresponding author:Zhang Li,wanghaibo014@126.com

Funds:Project supported by the National Natural Science Foundation of China (Grant No. WK2310000043) and the Science and Technology Program of the 13rd Five-Year Plan of Education Bureau of Jilin Province, China (Grant No. JJKH 20180860KJ).

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