The uniform and compact Fe-based amorphous alloy coating was prepared by active combustion high velocity air fuel (AC-HVAF) spray method. By tuning the parameters of AC-HVAF spray process, the influence of the spraying gun length, spraying distance, and powder feed rate on non-crystallization has been studied carefully. Results indicate that spraying gun length is the key factor in forming perfect amorphous coating. Spraying distance and powder feed rate may determine the thickness and formation rate of the coating. The prepared coatings have a tight adhesion with the substrate, low porosity, and good non-crystallization, which would effectively maintain the excellent mechanical properties of the Fe-based amorphous alloy. The coating can provide a good protection for the substrate material.