Gel propellant has the advantage of controllable flux as liquid propellant and long-term reservation as solid propellant, however, the evaporation and combustion problem of gel spray droplet bores with the gel propellant development and combustor design all the time, and hampers gel propellant practical engineering applications. In this paper, the gel single droplet combustion experiment system is designed and constructed, and then the evaporation and combustion mechanism is explored deeply based on the experimental phenomena of organic gel unsymmetrical dimethylhydrazine (UDMH) single droplet burning in nitrogen tetroxide. The organic gel spray droplet multi-component evaporation model is developed for three different evaporation phases of the gel layer, i.e. the forming, expanding and bursting of the gel layer based on the single droplet evaporation characteristics in experiment, and then the gel single droplet vaporization in high temperature gas phase is numerically simulated and compared with the result of conventional liquid droplet using the elementary model parameters and physic property parameters. The result shows that the gel content on the droplet surface increases slowly at the beginning of evaporation, however it would increase rapidly to a mass fraction of 95% and form the gel layer in a limited time after exceeding a critical evaporation time, which results in surface mass flux dropping to 0 and surface temperature reaching the UDMH boil point rapidly. After the gel layer forming, the droplet radius and surface UDMH vapor mass fraction exhibit oscillation as the swelling-bursting phenomena in experiment. The gel droplet surface temperature holds above the boil point and the mass flux of gel droplet inner boiling evaporation is stronger than the conventional liquid droplet surface steady evaporation which makes the life time of gel droplet much shorter.