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对四角或三角畸变立方晶场中的(3d)1离子,在已有的静电晶场理论的基础上,采用“集团模型”,进一步引入Γ∥, Γ⊥及K∥, K⊥,R∥, R⊥,并考虑Eg混入T2g,导出适用于四角或三角畸变立方晶场各种可能情况的g∥, g⊥公式。讨论了g∥, gFor the ions with a (3d)1 electron in a tetragonally or trigonally distorted cubic crystal field by taking the previous static crystal field theory as starting point, the Γ∥, Γ⊥ and K∥ K⊥, R∥ R⊥ are introduced further in terms of cluster model. E9 mixing into T29 is also considered. Then we derive the formulas of g∥ and g⊥ which can be used in all possible eases of tetragonally or trigonally distorted cubic crystal field.The variation of g∥ and g⊥ with the parameters has been discussed.A considerable peak appearing on the Δg-(d/λ0) curve has been discovered and further analysed.Bight EPE experimental results from literatures have been fitted and explained.
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