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在这篇论文里我们证明,与某些作者所了解的不同,我们的流体的容变粘滞弹性理论不仅仅是在结构弛豫的情况中有效,而是对所有三种弛豫——热弛豫、结构弛豫与化学弛豫——都是同样有效的。从我们的容变不可逆性方程可以推到Herzfeld与Rice原为热弛豫所假定的热不可逆性方程。又可以证明的是在化学弛豫的情况中我们的容变不可逆性方程也包含着Liebermann由分子运动理论考究所得到的化学不可逆性方程。关于这理论在声吸收及速变现象中的应用,我们证明利用适当的热力学考究便可以从我们的压缩性理论所给的结果直接推到在热弛豫情况下有效的Bourgin-Kneser方程及在化学弛豫情况下可以有效的Liebermann方程。这个推导并揭发出来Liebermann的声吸收方程仅对液体说可以是一个良好的近似。我们附带地指出,在气体的情况中,某些已发表的声吸收及速变的实量结果的准确度已可以使我们从这些结果来算定气体的静态与立刻两压缩系数β0及β∞,从而确定热容量的两比值γ0及γ∞与外态内态两热容量C(e)及C(i)。这样我们又能从这些结果取得一些有关分子构造及分子碰撞过程中能量转移的结论。最后,我们讨论了我们的容变粘滞系数的定义的适当性。In this paper it is shown that our volume visco-elastic theory of fluids is applicable not merely to the case of structural relaxation as apparently regarded by some authors, but is equallyapplicable to all three kinds of relaxations-thermal, structural and chemical. From our equationof irreversibility of volume change (4), is inferred the equation of thermal irreversibility (10) as originally assumed by Herzfeld and Rice for the case of thermal relaxation. Also, in the case of chemical relaxation, our equation of irreversibility of volume change is shown to imply the equation of chemical irreversibility (15) as obtained from kinetic considerations by Lieber-mann.Regarding application of this theory to sound absorption and dispersion phenomena, Bourgin-Kneser equations (29) and (33) for the case of thermal relaxation and Liebermann equation (43) for the case of chemical relaxation are shown to follow directly from the results of our theory of compressibilities when the appropriate thermodynamic considerations have been made. This derivation reveals that Liebermann equation of sound absorption can be a good approximation only for the case of liquids.It is pointed out in passing that the accuracy of certain existing sound absorption and dispersion measurements in the case of gases has already made it possible to determine from them the static and instantaneous compressibilities β0 and β∞ and hence the two ratios of heat capacities γ0 and γ∞ and the external and internal heat capacities C(e) and C(i), and thus to draw directly from them certain conclusions regarding the structure of the molecule and the processes of energy exchanges upon collisions.Finally, the appropriateness of our definition of volume viscosity is discussed.
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