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摘要

表面张力在纳米气溶胶颗粒的吸湿生长研究中具有重要意义, 然而现有实验方法不能对其准确测量. 本文基于分子动力学方法模拟了丁二酸气溶胶颗粒吸湿生长形成稳定液滴的动力学过程, 在此基础上, 建立模型计算了液滴的表面张力, 进而探究了温度、粒径和丁二酸浓度对纳米液滴表面张力的影响机制. 结果表明, 随着温度从260 K升高到320 K, 液滴内分子间作用力的减弱导致了液滴表面张力的减小, 且表面张力的减小程度随丁二酸浓度的增大而增大, 究其主要原因在于液滴中丁二酸分子的径向分布随温度和丁二酸浓度变化的差异; 随着粒径的增大, 液滴表面张力先增大后趋于定值, 且粒径对表面张力的显著影响区间随着丁二酸浓度的增大而缩短; 研究还发现, 丁二酸分子的表面活性导致液滴表面张力随着丁二酸浓度的增大而减小, 且减小趋势符合对数函数形式, 尤其是在粒径小于6.12 nm时, 同时, 基于Szyszkowski公式对液滴的表面张力进行了拟合. 本文研究成果能为气溶胶颗粒的吸湿生长和相关动力学过程预测理论及模型的改进提供参数依据.

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Abstract

The surface tension plays a significant role in the hygroscopicity of aerosol particles on a nanoscale. However, it cannot be obtained by using the existing measurement techniques. In this study, we simulate the hygroscopic growth of one single succinic acid (SA) particle by using the molecular dynamic (MD) method. Based on the MD simulation results, the surface tension of the stable SA-water droplet is calculated by using a numerical model. Furthermore, the influencing mechanisms of temperature, diameter and concentration of SA on the surface tension of the nanoscale droplet are investigated. The results show that with the temperature increasing from 260 K to 320 K, the surface tension of the droplet decreases, which is mainly caused by the weakening of the intermolecular forces inside the droplet. Besides, the sensitivity of the surface tension to the temperature increases with the increasing SA concentration, which can be explained by the effect of the temperature and the SA concentration on the radial distribution of SA molecules. With the increase of the particle diameter, the surface tension of droplet first increases and then tends to be constant. The normal components of the Irving-Kirkwood pressure tensors are calculated to explain the effect of diameter and SA on the surface tension. In addition, when the SA concentration is increased, the particle diameter range which has an obvious effect on the surface tension is reduced. Moreover, the surface tension of the nanodroplet is negatively correlated with the SA concentration, and the correlation fits into the logarithmic function form, especially for droplet with a diameter smaller than 6.12 nm. The Szyszkowski equation is employed to fit the relationship between SA concentration and the surface tension of droplet. These findings can provide parameter support for improving the theoretical model of particle hygroscopicity and related kinetic processes. This study emphasizes further research on the surface tension of nano-droplets with more complex components.

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作者及机构信息

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通信作者:张超,chaozhang@usst.edu.cn

基金项目:国家自然科学基金(批准号: 52106207)资助的课题

Authors and contacts

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Corresponding author:Zhang Chao,chaozhang@usst.edu.cn

Funds:Project supported by the National Natural Science Foundation of China (Grant No. 52106207)

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参考文献

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施引文献

下载: 全尺寸图片幻灯片

N_w	500	750	1000	2000	3000	4000	5000	6000
R_e/nm	1.528	1.751	1.926	2.427	2.780	3.061	3.296	3.504
σ_w/(mN·m^–1)	55.100	58.099	62.112	67.760	69.334	69.339	70.371	70.688
Γ_max/(10^–6mol·m^-2)	0.711	0.872	2.598	1.910	3.743	7.368	10.963	11.018
γ/(mol·L^-1)	0.074	0.123	1.363	1.274	1.297	4.326	6.366	6.755

下载: 导出CSV

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