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摘要

钙钛矿太阳电池简单的制备工艺、低廉的成本和优异的性能使其有望替代已产业化的硅太阳电池, 革新现有能源供给结构, 然而, 钙钛矿太阳电池的稳定性差制约了其产业化进程, 本文分别介绍了光辐照下, 钙钛矿薄膜内部本征的离子迁移行为和由此产生的磁滞、荧光淬灭/增强和电池失效问题; 以及典型的TiO ₂/钙钛矿界面的紫外光不稳定、空穴传输层和金属电极不稳定问题. 作为依光器件深刻理解其光辐照稳定性对顺利解决电池各种环境稳定性问题至关重要.

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Abstract

The low-cost, high-efficiency and easy fabrication of perovskite solar cells make them an ideal candidate for replacing industrialized silicon solar cells, and thus reforming the current energy supply structure. However, the industrialization of perovskite solar cells is now restricted due to its poor stability. In this article, the intrinsic ion migration behavior in the perovskite film under light irradiation is introduced, which is mainly responsible for hysteresis, fluorescence quenching/enhancement and the failure of solar cell. In addition, the typical ultraviolet light instability of TiO ₂/perovskite interface, and the light instability of hole transport layer and metal electrodes are also discussed subsequently. As a light-dependent device, improving its light radiation stability is essential for making it suitable to various environmental applications.

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作者及机构信息

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通信作者:李燕,li1988yan@163.com

基金项目:陕西省自然科学基础研究计划(批准号: 2019JQ-286, 2018JQ-5130)、陕西省教育厅科研计划(批准号: 19JK0660, 20JK0507)、西安交通大学金属材料强度国家重点实验室、西安石油大学《材料科学与工程》省级优势学科(批准号: YS37020203)和西安石油大学研究生创新与实践能力培养计划(批准号: YCS20212115)

Authors and contacts

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Corresponding author:Li Yan,li1988yan@163.com

Funds:Project supported by the Natural Science Foundation Research Project of Shaanxi Province, China (Grant Nos. 2019JQ-286, 2018JQ-5130), the Scientific Research Program Funded by Shaanxi Provincial Education Department, China (Grant Nos. 19JK0660, 20JK0507), the State Key Laboratory of Metal Material Strength of Xi'an Jiaotong University, China, the Materials Science and Engineering of Provincial Advantage Disciplines in Xi’an Shiyou University, China (Grant No. YS37020203), and the Postgraduate Innovation and Practical Ability Training Program of Xi'an Shiyou University, China (Grant No. YCS20212115)

文章全文: translate this paragraph

参考文献

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施引文献

下载: 全尺寸图片幻灯片

材料	迁移离子	E_A/eV	文献
MAPbI₃	I^–	0.58	[47]
	Pb²⁺	2.31
	MA⁺	0.84
MAPbI₃	I^–	0.19 ± 0.05	[49]
MAPbI₃	I^–	0.1	[50]
	Pb²⁺	0.8
	MA⁺	0.5
MAPbI₃	I^–	0.33	[16]
MAPbI₃	MA⁺	0.55	[16]
MAPbI₃	MA⁺	0.36	[18]
MAPbI₃	$ {\rm{I}}_{\rm{i}}^{0} $	0.06	[21]
	$ {\rm{I}}_{\rm{i}}^{-} $	0.08
	$ {\rm{I}}_{\rm{i}}^{-} $(e/h)	0.05
	$ {\rm{V}}_{\rm{I}}^{0} $	0.15
	$ {\rm{V}}_{\rm{I}}^{+} $	0.09
	$ {\rm{V}}_{\rm{I}}^{+} $(e/h)	0.15

下载: 导出CSV

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