\begin{document}$ \left( {\bar 2\;0\;1} \right)$\end{document}晶面取向的β型Ga2O3薄膜, 厚度在202.4—292.3 nm之间, 薄膜在450—800 nm范围可见光波段的透射率约为90%, 吸收边随着功率的增加先蓝移后红移, 带隙约为4.81—4.96 eV. 光致发光光谱分析表明, 该外延层薄膜在460 nm处产生蓝色发光. 本文发现溅射功率为160 W时引入籽晶层生长的β-Ga2O3薄膜具有最佳的结晶质量, 这一方法将为高质量β-Ga2O3薄膜的可控生长提供有益参考."> - 必威体育下载

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    洪梓凡, 陈海峰, 贾一凡, 祁祺, 刘英英, 过立新, 刘祥泰, 陆芹, 李立珺, 王少青, 关云鹤, 胡启人

    Characteristics of Ga2O3epitaxial films on seed layer grown by magnetron sputtering

    Hong Zi-Fan, Chen Hai-Feng, Jia Yi-Fan, Qi Qi, Liu Ying-Ying, Guo Li-Xin, Liu Xiang-Tai, Lu Qin, Li Li-Jun, Wang Shao-Qing, Guan Yun-He, Hu Qi-Ren
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    • 氧化镓(Ga 2O 3)薄膜在功率器件以及紫外探测等领域中具有重要的应用潜力, 而实现高质量薄膜制备则是其中的关键. 本文在蓝宝石衬底上物理溅射生长外延Ga 2O 3层, 因采用引入籽晶层的方法提供了人为成核点而使得外延层结晶质量获得明显改善. 实验发现该外延层薄膜的生长中随着功率增加, 晶粒团聚到一定尺寸后出现裂解现象. 这一物理机制归因于大功率下溅射粒子在生长晶面上扩散携带的能量过大导致粒子碰撞次数增多. 文中生长的外延层为 $ \left( {\bar 2\;0\;1} \right)$ 晶面取向的β型Ga 2O 3薄膜, 厚度在202.4—292.3 nm之间, 薄膜在450—800 nm范围可见光波段的透射率约为90%, 吸收边随着功率的增加先蓝移后红移, 带隙约为4.81—4.96 eV. 光致发光光谱分析表明, 该外延层薄膜在460 nm处产生蓝色发光. 本文发现溅射功率为160 W时引入籽晶层生长的β-Ga 2O 3薄膜具有最佳的结晶质量, 这一方法将为高质量β-Ga 2O 3薄膜的可控生长提供有益参考.
      Gallium oxide (Ga 2O 3) thin films have great potential applications in UV detectors and power devices; the preparation of high-quality films still needs further studying. In this paper, the Ga 2O 3epitaxial thin films are grown by physical sputtering on the seed layer under different power conditions, and the growth mechanism of Ga 2O 3epitaxial films are investigated. The introduction of a seed layer provides an artificial nucleation point, which effectively alleviates the lattice mismatch between sapphire substrate and Ga 2O 3epitaxial films. thereby improving the quality of the epitaxial layer significantly. Through experiments, it is found that as the power of the epitaxial layer film increases during the growth, the crystal grains agglomerate to a certain size and crack. This physical phenomenon is attributed to the fact that the energy carried by sputtered particles is too large under the condition of high power, which leads the number of particle collisions to increase when they diffuse on the growing crystal surface. The X-ray diffraction, atomic force microscope, field emission scanning electron microscope, ultraviolet spectrophotometer, and photo-luminescence spectrum are used to characterize the structure, morphology, and optical properties of the deposited Ga 2O 3thin film. The results show that the epitaxial films are β-Ga 2O 3with $ \left( {\bar 2\;0\;1} \right)$ orientation, and the thickness values of thin films are between 202.4 and 292.3 nm. Comparing with the Ga 2O 3thin films grown directly on sapphire, the surface particle size increases significantly and the crystal quality is improved greatly under the condition of seed layer. The surface roughness is still maintained at a lower value reaching the device preparation standard. All Ga 2O 3epitaxial films show that they have the high transmittance of about 90% in the visible light region (450-800 nm) and drop sharply at 350-400 nm. As the power increases, the absorption edge is blue-shifted and then red-shifted. The estimated band gap is about 4.81-4.96 eV. The PL spectra show that thin films produce blue emission only at 460 nm. It is found that the Ga 2O 3films grown on seed layer at a sputtering power of 160 W have the excellent crystal quality. The results should be helpful in implementing the controllable preparation of high-quality β-Ga 2O 3thin films in the future.
          通信作者:陈海峰,chenhaifeng@xupt.edu.cn
        • 基金项目:陕西省自然科学基础研究计划(批准号: 2020JM-581)资助的课题
          Corresponding author:Chen Hai-Feng,chenhaifeng@xupt.edu.cn
        • Funds:Project supported by the Natural Science Basic Research Program of Shaanxi Province, China (Grant No. 2020JM-581)
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      出版历程
      • 收稿日期:2020-05-29
      • 修回日期:2020-07-04
      • 上网日期:2020-11-09
      • 刊出日期:2020-11-20

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